Synthesis of neopentyl derivatives of triphenyl carbinol and the kinetics of Bamberger's reaction
Rowe, Paul Edward
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The following new compounds were prepared by adaptations of standard methods: p-neopentylphenyldiphenyl carbinol, di-p-neopentylphenylphenyl carbinol, tri-p-neopentylphenyl carbinol, m-neopentylphenyldiphenyl carbinol, and di-m-neopentylphenylphenylmethyl chloride. The preparation of tri-m-neopentylphenyl carbinol was attempted unsuccessfully. Other compounds prepared for the first time as intermediates in these preparations are o- and p-nitroneopentylbenzene, o- and p-aminoneopentylbenzene, o-acetaminoneopentylbenzene, m-bromoneopentylbenzene, 3,5-di-bromoneopentylbenzene, 3-bromo-4-acetaminoneopentylbenzene, 3-bromo-4-aminoneopentylbenzene, p-bromoneopentylbenzene, p,p'-dineopentylbiphenyl, and ethyl-p-neopentylphenyldiphenylmethyl ether. [TRUNCATED]
Thesis (M.S.)--Boston University
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