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dc.contributor.authorGervais, Anaisen_US
dc.contributor.authorLazarski, Kiel E.en_US
dc.contributor.authorPorco, John A.en_US
dc.coverage.spatialUnited Statesen_US
dc.date.accessioned2018-01-30T16:48:08Z
dc.date.available2018-01-30T16:48:08Z
dc.date.issued2015-10-02
dc.identifierhttps://www.ncbi.nlm.nih.gov/pubmed/26351970
dc.identifier.citationAnais Gervais, Kiel E Lazarski, John A Porco. 2015. "Divergent Total Syntheses of Rhodomyrtosones A and B.." J Org Chem, Volume 80, Issue 19, pp. 9584 - 9591.
dc.identifier.issn1520-6904
dc.identifier.urihttps://hdl.handle.net/2144/26494
dc.description.abstractHerein, we report total syntheses of the tetramethyldihydroxanthene natural product rhodomyrtosone B and the related bis-furan β-triketone natural product rhodomyrtosone A. Nickel-(II)-catalyzed 1,4-conjugate addition of an α-alkylidene-β-dicarbonyl substrate was developed to access the congener rhodomyrtosone B, and oxygenation of the same monoalkylidene derivative followed by cyclization was employed to obtain the bis-furan natural product rhodomyrtosone A.en_US
dc.description.sponsorshipR01 GM073855 - NIGMS NIH HHS; R24 GM111625 - NIGMS NIH HHS; GM111625 - NIGMS NIH HHSen_US
dc.format.extent9584 - 9591en_US
dc.languageeng
dc.relation.ispartofJ Org Chem
dc.subjectScience & technologyen_US
dc.subjectPhysical sciencesen_US
dc.subjectChemistry, organicen_US
dc.subjectChemistryen_US
dc.subjectOrtho-quinone methidesen_US
dc.subjectFlow photochemistryen_US
dc.subjectConjugate additionen_US
dc.subjectMeldrums acidsen_US
dc.subjectAcylphloroglucinolsen_US
dc.subjectEndoperoxidesen_US
dc.subjectTomentosaen_US
dc.subjectBiological productsen_US
dc.subjectCatalysisen_US
dc.subjectCyclizationen_US
dc.subjectFuransen_US
dc.subjectHeterocyclic compounds, 3-ringen_US
dc.subjectKetonesen_US
dc.subjectMolecular structureen_US
dc.subjectNickelen_US
dc.subjectStereoisomerismen_US
dc.subjectMedicinal and biomolecular chemistryen_US
dc.subjectOrganic chemistryen_US
dc.subjectInorganic chemistryen_US
dc.titleDivergent total syntheses of rhodomyrtosones A and Ben_US
dc.typeArticleen_US
dc.identifier.doi10.1021/acs.joc.5b01570
pubs.elements-sourcepubmeden_US
pubs.notesEmbargo: Not knownen_US
pubs.organisational-groupBoston Universityen_US
pubs.organisational-groupBoston University, College of Arts & Sciencesen_US
pubs.organisational-groupBoston University, College of Arts & Sciences, Department of Chemistryen_US
pubs.publication-statusPublisheden_US


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