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dc.contributor.authorGallo, Paolaen_US
dc.contributor.authorArnann-Winkel, Katrinen_US
dc.contributor.authorAngell, Charles Austenen_US
dc.contributor.authorAnisimov, Mikhail Alexeevichen_US
dc.contributor.authorCaupin, Fredericen_US
dc.contributor.authorChakravarty, Charusitaen_US
dc.contributor.authorLascaris, Eriken_US
dc.contributor.authorLoerting, Thomasen_US
dc.contributor.authorPanagiotopoulos, Athanassios Zoisen_US
dc.contributor.authorRusso, Johnen_US
dc.contributor.authorSellberg, Jonas Alexanderen_US
dc.contributor.authorStanley, Harry Eugeneen_US
dc.contributor.authorTanaka, Hajimeen_US
dc.contributor.authorVega, Carlosen_US
dc.contributor.authorXu, Limeien_US
dc.contributor.authorPettersson, Lars Gunnar Moodyen_US
dc.date.accessioned2020-04-01T19:21:13Z
dc.date.available2020-04-01T19:21:13Z
dc.date.issued2016-07-13
dc.identifierhttp://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000379794000002&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=6e74115fe3da270499c3d65c9b17d654
dc.identifier.citationPaola Gallo, Katrin Arnann-Winkel, Charles Austen Angell, Mikhail Alexeevich Anisimov, Frederic Caupin, Charusita Chakravarty, Erik Lascaris, Thomas Loerting, Athanassios Zois Panagiotopoulos, John Russo, Jonas Alexander Sellberg, Harry Eugene Stanley, Hajime Tanaka, Carlos Vega, Limei Xu, Lars Gunnar Moody Pettersson. 2016. "Water: A Tale of Two Liquids." CHEMICAL REVIEWS, Volume 116, Issue 13, pp. 7463 - 7500 (38). https://doi.org/10.1021/acs.chemrev.5b00750
dc.identifier.issn0009-2665
dc.identifier.issn1520-6890
dc.identifier.urihttps://hdl.handle.net/2144/39928
dc.description.abstractWater is the most abundant liquid on earth and also the substance with the largest number of anomalies in its properties. It is a prerequisite for life and as such a most important subject of current research in chemical physics and physical chemistry. In spite of its simplicity as a liquid, it has an enormously rich phase diagram where different types of ices, amorphous phases, and anomalies disclose a path that points to unique thermodynamics of its supercooled liquid state that still hides many unraveled secrets. In this review we describe the behavior of water in the regime from ambient conditions to the deeply supercooled region. The review describes simulations and experiments on this anomalous liquid. Several scenarios have been proposed to explain the anomalous properties that become strongly enhanced in the supercooled region. Among those, the second critical-point scenario has been investigated extensively, and at present most experimental evidence point to this scenario. Starting from very low temperatures, a coexistence line between a high-density amorphous phase and a low-density amorphous phase would continue in a coexistence line between a high-density and a low-density liquid phase terminating in a liquid–liquid critical point, LLCP. On approaching this LLCP from the one-phase region, a crossover in thermodynamics and dynamics can be found. This is discussed based on a picture of a temperature-dependent balance between a high-density liquid and a low-density liquid favored by, respectively, entropy and enthalpy, leading to a consistent picture of the thermodynamics of bulk water. Ice nucleation is also discussed, since this is what severely impedes experimental investigation of the vicinity of the proposed LLCP. Experimental investigation of stretched water, i.e., water at negative pressure, gives access to a different regime of the complex water diagram. Different ways to inhibit crystallization through confinement and aqueous solutions are discussed through results from experiments and simulations using the most sophisticated and advanced techniques. These findings represent tiles of a global picture that still needs to be completed. Some of the possible experimental lines of research that are essential to complete this picture are explored.en_US
dc.description.sponsorshipThis review was initiated during the Nordita (Nordic Institute for Theoretical Physics) scientific program "Water-the Most Anomalous Liquid". Additional financial support for this program was provided by the Royal Swedish Academy of Sciences through its Nobel Institutes for Physics and Chemistry, by the Swedish Research Council, and by the Department of Physics at Stockholm University. We would like to acknowledge helpful suggestions by Prof. Pablo Debenedetti. We are grateful to Stephan Fuhrmann for providing Figure 4. C.A.A. wishes to acknowledge support from the NSF under collaborative grant no. CHE 12-13265. F.C. acknowledges funding by the European Research Council under the European Community's FP7 Grant Agreement 240113 and by the Agence Nationale de la Recherche Grant 09-BLAN-0404-01. C.C. would like to thank the Department of Science and Technology, New Delhi, for financial support. T.L. is grateful for funding from the European Research Council (ERC Starting Grant SULIWA), the Austrian Science Fund FWF (bilateral project I1392), the Austrian research promotion agency FFG (Bridge-project EarlySnow), and the Alexander von Humboldt Foundation (Bessel award). A.Z.P. would like to acknowledge support for this work by the Department of Energy, Office of Basic Energy Sciences, under Award No. DE-SC0002128. H.T. acknowledges supports from Grants-in-Aid for Scientific Research (5) (grant no. 21224011) and Specially Promoted Research (grant no. 25000002) from the Japan Society for the Promotion of Science. C.V. acknowledges project FIS2013-43209-P for funding. L.X. acknowledges support from the National Science Foundation of China (grant nos. 11174006, 11290162, 11525520) and MOST (grant nos. 2012CB921404 and 2015CB856801). (Royal Swedish Academy of Sciences through Nobel Institutes for Physics and Chemistry; Swedish Research Council; Department of Physics at Stockholm University; CHE 12-13265 - NSF; 240113 - European Research Council under the European Community's FP7 Grant; 09-BLAN-0404-01 - Agence Nationale de la Recherche; Department of Science and Technology, New Delhi; European Research Council (ERC Starting Grant SULIWA); I1392 - Austrian Science Fund FWF; Austrian research promotion agency FFG (Bridge-project EarlySnow); Alexander von Humboldt Foundation; DE-SC0002128 - Department of Energy, Office of Basic Energy Sciences; 21224011 - Japan Society for the Promotion of Science; 25000002 - Japan Society for the Promotion of Science; 11174006 - National Science Foundation of China; 11290162 - National Science Foundation of China; 11525520 - National Science Foundation of China; 2012CB921404 - MOST; 2015CB856801 - MOST; FIS2013-43209-P)en_US
dc.format.extentp. 7463 - 7500en_US
dc.languageEnglish
dc.language.isoen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.relation.ispartofCHEMICAL REVIEWS
dc.rights© 2016 American Chemical Society. This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. View the license here: https://pubs.acs.org/page/policy/authorchoice_termsofuse.html.en_US
dc.subjectScience & technologyen_US
dc.subjectPhysical sciencesen_US
dc.subjectChemistry, multidisciplinaryen_US
dc.subjectChemistryen_US
dc.subjectHomogeneous ice nucleationen_US
dc.subjectDensity amorphous iceen_US
dc.subjectNo-mans-landen_US
dc.subjectSupercooled confined wateren_US
dc.subjectUniversal scaling lawen_US
dc.subjectTo-strong transitionen_US
dc.subjectEquation-of-stateen_US
dc.subjectHyperquenched glassy wateren_US
dc.subjectStokes-Einstein relationen_US
dc.subjectAlkali-halide solutionsen_US
dc.subjectGeneral chemistryen_US
dc.subjectChemical sciencesen_US
dc.titleWater: a tale of two liquidsen_US
dc.typeArticleen_US
dc.description.versionPublished versionen_US
dc.identifier.doi10.1021/acs.chemrev.5b00750
pubs.elements-sourceweb-of-scienceen_US
pubs.notesEmbargo: Not knownen_US
pubs.organisational-groupBoston Universityen_US
pubs.organisational-groupBoston University, College of Arts & Sciencesen_US
pubs.organisational-groupBoston University, College of Arts & Sciences, Department of Physicsen_US
pubs.publication-statusPublisheden_US
dc.identifier.mycv92951


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