Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) Dimethyl Sulfoxide Solvate
Date
2009-8-26
Authors
Kahn, Michael I.
Golen, James A.
Rheingold, Arnold L.
Doerrer, Linda H.
Version
OA Version
Citation
Kahn, Michael I., James A. Golen, Arnold L. Rheingold, Linda H. Doerrer. "Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate" Acta Crystallographic 65(Pt 9):m1135. (2009)
Abstract
The crystal structure of the title compound, [PtBr(C15H11N3)][AuBr2]·(CH3)2SO, exhibits infinite chains of {PtAuPt}∞ metallophilic interactions along the b axis. Two cations and one anion stack in a trimer with a unique Pt·Au distance of 3.3361 (5) Å and Pt·Pt contacts of 3.4335 (6) Å. The remaining [AuBr2]− anion forms no close contacts.
Description
License
Copyright Kahn et al. 2009 This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.