Bromido(2,2':6',2''-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate.
Files
Published version
Date
2009-08-26
Authors
Kahn, Michael I.
Golen, James A.
Rheingold, Arnold L.
Doerrer, Linda H.
Version
OA Version
Citation
Michael I. Kahn, James A. Golen, Arnold L. Rheingold, Linda H. Doerrer. 2009. "Bromido(2,2':6',2''-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate.." Acta Crystallogr Sect E Struct Rep Online, v. 65, Issue Pt. 9, pp. m1135 (11).
Abstract
The crystal structure of the title compound, [PtBr(C(15)H(11)N(3))][AuBr(2)]·(CH(3))(2)SO, exhibits infinite chains of {PtAuPt}(∞) metallophilic inter-actions along the b axis. Two cations and one anion stack in a trimer with a unique Pt⋯Au distance of 3.3361 (5) Å and Pt⋯Pt contacts of 3.4335 (6) Å. The remaining [AuBr(2)](-) anion forms no close contacts.